Unraveling specific role of carbon matrix over Pd/quasi-Ce-MOF facilitating toluene enhanced degradation

Metal organic frameworks (MOFs) derivatives represented by quasi-MOFs have excellent physical and chemical properties and can be applied for the catalytic combustion of volatile organic compounds (VOCs). In this work, Pd/quasi-Ce-BTC synthesized by simple one-step N₂ pyrolysis was applied to the oxidation of toluene, showing excellent toluene catalytic activity (T₉₀ = 175 °C, 30000 mL/(g·h)). Microscopic analyses indicate the formation and interaction of a carbon matrix composite quasi-MOF structure interface. The results show that the amorphous carbon matrix formed during the partial pyrolysis of Ce-BTC significantly improves the adsorption and activation capacity of toluene in the reaction, and constructs a reductive system to maintain high concentrations of Ce³⁺ and Pd⁰, which can facilitate the activation and utilization of oxygen in reaction. Quasi in-situ XPS proves that carbon matrix is indirectly involved in the activation and storage of oxygen, and Pd⁰ is the crucial active site for the activation of oxygen. Stability and water resistance tests display good stability of Pd/quasi-Ce-BTC. This work provides a potential method for designing quasi-MOF catalysts towards VOCs effective abatement.     

基于CiteSpace的资源型产业研究知识图谱分析

资源型产业发展为推进国家经济增长和工业化进程提供了重要保障。为深入了解资源型产业的研究情况，以CNKI数据库为数据源，搜集2000—2020年关于资源型产业的核心及以上期刊论文，利用CiteSpace软件从发文作者与研究机构分布、关键词共现网络和时区图谱等方面，绘制知识图谱，进行可视化分析。研究发现：资源型产业领域的研究成果愈加丰富，但研究群体间联系合作较少，且现有的合作研究主要集中在所处地域资源富集和具有学科优势的研究机构及学者；资源型产业领域的研究热点可概括为产业发展、资源型城市、产业集群、产业结构、产业链和产业集聚等方面；针对资源型产业领域未来可从资源型产业相关理论研究、创新发展模式和可持续发展等方面深入展开。     

The thermochromic characteristics of Zn-doped VO2 that were prepared by the hydrothermal and post-annealing process and their polyurethane composite films

In this paper, Zn-doped VO₂ nanoparticles have been successfully fabricated by a two-step hydrothermal-annealing process, and the thermally induced visible light transmittance enhancement of Zn-doped VO₂ has been studied for the first time. It is found that Zn-doped VO₂ not only exhibits excellent solar modulation ability (ΔT_sol = 15.27%) but also can reduce the phase transition temperature and increase the visible light transmittance after the heat-induced phase transition (ΔT_lum=+5.78%). Moreover, with the increase of Zn doping concentration, the phase transition temperature (T_c) and phase transition hysteresis (ΔT) both decrease. It is shown that the Zn-doped VO₂-PU films not only have good solar light modulation ability and properties of improving visible light transmission after phase transition, but also have good durability. The research result is of great significance for improving the visible light transmittance after phase transition and realizing the practical application of VO₂ in the field of smart windows.     

以 提高实践能力为目标的数据结构课程教学改革探索

This paper analyzes the problems existing in the teaching of data structure course, and puts forward the reform from the as- pects of strengthening basic programming, visualized explanation of abstract theory, combination of C++, Java programming, ratio- nal use of online platform, and stratification of exercises, aiming at improving students' practical ability, learning interest and self- confidence.     

User idea implementation in open innovation communities: Evidence from a new product development crowdsourcing community

In collaborative crowdsourcing communities for open innovation, users generate and submit ideas as idea co‐creators. Firms then select and implement valuable ideas for new product development. Despite the popularity and success of these open innovation communities, relatively little is known about the factors that determine the implementation of the user‐generated ideas. Based on research on individual creativity, we propose a conceptual model integrating users' previous experience, idea presentation characteristics and feedback valence to explain the likelihood of idea implementation. We validate our research model with a panel data analysis of 43 550 ideas submitted by 16 360 users in the MIUI new product development community hosted by Xiaomi, a large electronics manufacturing company in China. We find an inverted U‐shaped relationship between users' past successful experience and idea implementation. Furthermore, the length of ideas is positively associated with the likelihood of idea implementation. There is also an inverted U‐shaped relationship between supporting evidence and idea implementation. Finally, we demonstrate the negative effect of positive feedback and the positive effect of negative feedback on idea implementation. These findings offer rich insights to understand the phenomenon of open innovation better. Theoretical and practical implications are discussed.     

大学生创新能力培养模式的探索与实践

研究创新人才培养规律,探索和实践创新人才培养模式,是当前高校教育教学改革的一个重要方向。针对我校自动化专业立足国防、面向社会的人才培养特色,提出了以“创新意识、创新精神、创新技能”为核心的学生创新能力培养理念,通过构建创新能力培养“全链”模式、优化创新能力培养的“微生态”环境,取得了突出的成效。     

中国省际绿色技术创新效率测度及影响因素研究

文章基于2011—2017年中国30个省份面板数据，运用super-SBM模型对绿色技术创新效率进行测算，并利用ML指数对绿色技术创新效率进行动态分析，最后通过空间滞后模型分析影响效率的关键因素。研究结果表明：中国绿色技术创新效率呈逐渐增长的趋势，但整体效率偏低，有较大进步空间；中国绿色技术创新效率存在明显区域差异，呈现由东部向西部递减的格局；绿色技术创新水平的提高是技术效率和技术进步共同贡献的结果；产业结构、区域开放程度和教育水平对绿色技术创新效率产生积极的正向影响，环境规制和研发投入强度对绿色技术创新效率影响不显著。     

Tunable Spectrum Selectivity for Multiphoton Absorption with Enhanced Visible Light Trapping in ZnO Nanorods

Observation of visible light trapping in zinc oxide (ZnO) nanorods (NRs) correlated to the optical and photoelectrochemical properties is reported. In this study, ZnO NR diameter and c‐axis length respond primarily at two different regions, UV and visible light, respectively. ZnO NR diameter exhibits UV absorption where large ZnO NR diameter area increases light absorption ability leading to high efficient electron–hole pair separation. On the other hand, ZnO NR c‐axis length has a dominant effect in visible light resulting from a multiphoton absorption mechanism due to light reflection and trapping behavior in the free space between adjacent ZnO NRs. Furthermore, oxygen vacancies and defects in ZnO NRs are associated with the broad visible emission band of different energy levels also highlighting the possibility of the multiphoton absorption mechanism. It is demonstrated that the minimum average of ZnO NR c‐axis length must satisfy the linear regression model of Z _p,min = 6.31d to initiate the multiphoton absorption mechanism under visible light. This work indicates the broadening of absorption spectrum from UV to visible light region by incorporating a controllable diameter and c‐axis length on vertically aligned ZnO NRs, which is important in optimizing the design and functionality of electronic devices based on light absorption mechanism.     

The influence of national culture on responsible innovation: A case of CO2 utilisation in Indonesia

Responsible innovation (RI) offers a promising step towards a more responsible adoption of innovations, such as new and emerging technologies. However, how RI would be practised in different cultural contexts and settings is still less studied, especially in the context of developing countries. Taking the utilisation of CO₂ in Indonesia as an empirical case, the purpose of this paper is to explore this issue through examining the influence of key characteristics of Indonesia's national culture on core dimensions of RI: anticipation, reflexivity, deliberation, responsiveness and participation. The different RI dimensions are applied in practice in a focus group discussion (FGD) and a round of interviews with different stakeholders that explored CO₂ utilisation in the country. Hofstede's classification of national cultural dimensions is used to single out key focus points for attention in these RI processes in the Indonesian context. The results from the experiment illustrate that culture matters in the application of RI dimensions in practice. In the sense that in order for RI to work well, the governance of core RI processes such as participation and deliberation has to be adjusted to social norms of what is considered legitimate, desirable and good behaviour. These norms differ across societies. The findings further suggest ways of applying RI dimensions in practice.     

Effect of cerium oxide prepared under different hydrothermal time on electrocatalytic performance of Pt-based anode catalysts

In this paper,CeO_2 with a pore size of 2-4 nm was synthesized by hydrothermal method.The CeO_2 modified graphene-supported Pt catalyst was prepared by the microwave-assisted ethylene glycol reduction chloroplatinic acid method,and the effect of the addition of CeO_2 prepared by different hydrothermal reaction time on the catalytic performance of Pt-based catalysts was investigated.The microstructures of CeO_2 and catalysts were characterized by X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),specific surface area and pore size analyzer(BET),scanning electron microscopy(SEM) and electron spectroscopy(EDAX),transmission electron microscopy(TEM),and the catalysts electrochemical performance was tested by electrochemical workstation.The results show that the catalytic performance of the four catalysts with CeO_2 is better than that of the catalyst without CeO_2.Adding CeO_2 with a specific surface area of 120.15 m~2/g prepared by hydrothermal reaction time of 39 h to Pt/C synthesis catalyst,its electrocatalytic performance,stability and resistance to poisoning are the best.The electrochemical active surface area is 102.83 m~2/g,the peak current density of ethanol oxidation is 757.17 A/g and steady-state current density of 1100 s is 108.17 A/g which shows the lowest activation energy for ethanol oxidation reaction.When the cyclic voltammogram is scanned for 500 cycles,the oxidation peak current density retention rate is 87.74%.